Degradation of NiCr/CuNiMn/NiCr films on alumina substrates

This paper addresses the aging behaviour of NiCr/CuNiMn/NiCr triple layers on Al₂O₃ ceramics at temperatures up to 200°C for film thicknesses d0.5 μm. Investigations of the film structure and the increase of resistance and its temperature coefficient during the annealing process and studies of the dependence of this aging drift on both the film thickness and the storage temperature have been carried out. Furthermore, the film stress and the effect of substrate bending on resistance have been measured. The results can be explained by the irregular film structure (columns and small bridges between them), which causes stress and current concentrations as well as local creeping, cracking and oxidation processes in the micro-bridges. They are compared with such for structurally homogeneous films on silicon wafers.     

含能材料分子结构与感度的相关性

综述了国外近年来含能材料分子结构参数与感度相关关系的最新研究成果。研究表明：某些芳香族硝基化合物的撞击感度与Ｃ－ＮＯ２键强度有关；硝胺及脂肪族硝基化合物的冲击波感度与分子中Ｎ－ＮＯ２键的数目，长度和分子量相关。     

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本文简要介绍了国外在开发超酸性气体过程中遇到的材料选择、腐蚀监测、水化物堵塞、超酸性气的处理和加工等问题所采取的措施和办法。     

Production and properties of micro‐porous glas bubble zinc and aluminium composites

Micro‐porous syntactic foams were produced by means of integration of glass bubbles into aluminium and zinc matrices. Preforms of glass bubbles were pressure infiltrated with the alloys AlSi9Cu9 ans ZnAl4Cu using squeeze casting. The preforms were sintered thermically without the use of bonding agents. Using the combination of different sintering steps syntactic foams with locally different densities could be produced. The mechanical properties of the foams were tested indicating a high compression strength of the foams and a very good compression energy absorption. Furthermore, corrosion behaviour and behaviour at higher temperatures were investigated.     

泡沫铝的动态压缩性能和吸能性研究

通过测量泡沫铝在动态和准静态压缩条件下的应力 -应变曲线 ,研究了泡沫铝的准静态和动态压缩行为以及不同应变条件下的吸能性 ,并对其应变率效应进行了分析。结果表明 ,在高应变速率和准静态压缩下 ,泡沫铝的σ -ε曲线均表现出弹性变形段、平缓段和密实段三阶段特征 ;泡沫铝的压缩性能具有明显的应变速率敏感性 ,随应变速率的提高 ,流动应力上升 ,吸能性升高     

如何正确选择合适的耐蚀材料

文章较全面的介绍了如何根据设备、装置、构件所处的工作环境及使用条件进行防腐蚀设计,及其防腐蚀设计的内容和注意事项,选择合适的防腐蚀材料,确保产品的使用寿命     

Validity of dynamic electrochemical impedance spectra of some amine corrosion inhibitors in petroleum/water corrosive mixtures by Kramers-Kronig transformation

In our previous works, the corrosion inhibition properties of propylamine (PA), iso-propylamine (i-PA), butylamine (BA), tert-butylamine (t-BA), hexylamine (HA), ethylenediamine (EDA), diethanolamine (DEA), 3-amino-1-propanol (3-AP), 2-dimethylethanolamine (2-DEA), cyclohexylamine (CHA), N-methylcyclohexylamine (N-MCA) and dicyclohexylamine (DCHA) have been investigated by means of electrochemical impedance spectroscopy (EIS) with a carbon steel rotating disc electrode in some petroleum/water corrosive mixtures containing acetic acid and NaCl at 25 °C. In this work, the Kramers-Kronig transformations (KKTs) were applied to evaluate the validity of the impedance data of these amine compounds in hydrodynamic condition. The results obtained showed that experimental impedance data did not satisfy in K-K relations completely viz. indicated some errors. These errors were related to stray capacitances, external transmission line effects, pits formation and change in interface during data acquisition at high and low frequencies regions. In addition, the selection of a suitable equivalent circuit strongly emphasized to better interpret of EIS data which in turn cause better resulted KKTs spectra. With considering obtained transformations, more effective inhibitor was selected with regard to its charge transfer resistance, the corrosion capacitance and well satisfying in K-K relations.     

考虑抗力退化的公路钢筋混凝土梁抗弯强度可靠性分析

本文采用了一个时变荷载模型和一个考虑了钢筋锈蚀，钢筋屈服拉力，混凝土抗压强度和粘结力等多个影响因素的多参数抗力劣化模型，对公路钢筋混凝土梁抗弯强度可靠性在服役期内的变化趋势进行了研究，并针对一实例对各影响参数对可靠性分析的敏感性进行了分析。     

Corrosion Behavior of a Sputtered K38G Nanocrystalline Coating with a Solid NaCl Deposit in Wet Oxygen at 600 to 700°C

A nanocrystalline coating of K38G alloy was obtained by means of magnetron sputtering. The corrosion behavior of cast K38G alloy and its sputtered nanocrystalline coating with a solid NaCl deposit in dry air or wet oxygen at 600 and 700°C have been studied and compared. The results indicated that the mass gain of the coating is higher than that of the cast alloy at 600 and 700°C. Therefore, nanocrystallization reduced the corrosion resistance at these temperatures. Furthermore, the mass gains of the coating and the cast alloy with a NaCl deposit in wet oxygen were less than that with a NaCl deposit in dry air. The relevant corrosion mechanisms are discussed.     

蒸馏与减粘热联合装置的设备腐蚀及防护

介绍了锦西石化分公司南蒸馏与减粘热联合装置炼制辽河高酸值原油及带炼高硫进口油在 2 0 0～40 0℃范围内对设备、管线和阀门的腐蚀特点、腐蚀机理以及针对高温环烷酸腐蚀所采取的防护措施。通过试验和理论分析 ,提出了应用新材料和新工艺解决减粘后高温渣油系统的腐蚀及低温露点腐蚀的建议